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- Title
Room-temperature.
- Authors
Wang, Fuzhou; Tanaka, Ryo; Cai, Zhengguo; Nakayama, Yuushou; Shiono, Takeshi
- Abstract
An α-diimine Pd(II) complex containing chiral sec-phenethyl groups, {bis[ N, N′-(4-methyl-2- sec-phenethylphenyl)imino]-2,3-butadiene}dichloropalladium ( rac- C1), was synthesized and characterized. rac- C1 was applied as an efficient catalyst for the between various aniline halides and arylboronic acid in PEG-400-H2O at room temperature. Among a series of aniline halides, rac- C1 did not catalyze the of aniline chlorides and fluorides but efficiently catalyzed the of aniline bromides and iodides with phenylboronic acid. The reduced slightly with increasing steric hindrance of the aniline bromides. The complexes {bis[ N, N′-(4-fluoro-2,6-diphenylphenyl)imino]-2,3-butadiene}dichloropalladium and {bis[ N, N′-(4-fluoro-2,6-diphenylphenyl)imino]acenaphthene}dichloropalladium were also found to be efficient catalysts for the reaction. Copyright © 2015 John Wiley & Sons, Ltd.
- Subjects
IMINES; ENANTIOSELECTIVE catalysis; STYRENE; BUTADIENE; ANILINE
- Publication
Applied Organometallic Chemistry, 2015, Vol 29, Issue 11, p771
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.3365