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- Title
Stereoselective Electro‐2‐deoxyglycosylation from Glycals.
- Authors
Liu, Miao; Liu, Kai‐Meng; Xiong, De‐Cai; Zhang, Hanyu; Li, Tian; Li, Bohan; Qin, Xianjin; Bai, Jinhe; Ye, Xin‐Shan
- Abstract
We report a novel and highly stereoselective electro‐2‐deoxyglycosylation from glycals. This method features excellent stereoselectivity, scope, and functional‐group tolerance. This process can also be applied to the modification of a wide range of natural products and drugs. Furthermore, a scalable synthesis of glycosylated podophyllotoxin and a one‐pot trisaccharide synthesis through iterative electroglycosylations were achieved.
- Subjects
GLYCALS; NATURAL products; PODOPHYLLOTOXIN; STEREOSELECTIVE reactions
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 35, p15316
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202006115