We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Excess molar enthalpies of binary mixtures for (tributyl phosphate+methanol/ethanol) at 298.15 K.
- Authors
Liu, H.-L.; Liu, S.-J.; Xiao, Z.-L.; Chen, Q.-Y.; Yang, D.-W.
- Abstract
Excess molar enthalpies of binary mixtures for tributyl phosphate (TBP)+methanol/ethanol were measured with a TAM air Isothermal calorimeter at 298.15 K and ambient. The results for xTBP+(1– x)CH3OH are negative in the whole range of composition, while the values for xTBP+(1– x)C2H5OH change from positive values at low x to small negative values at high x. The experimental results have been correlated with the Redlich–Kister polynomial. IR spectra of the mixtures were measured to investigate the effect of hydrogen bonding in the mixture.
- Subjects
ENTHALPY; TRIBUTYL phosphate; METHANOL; ALCOHOL; CALORIMETERS; HYDROGEN bonding
- Publication
Journal of Thermal Analysis & Calorimetry, 2006, Vol 85, Issue 3, p541
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-006-7635-x