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- Title
Thermodynamic study of the SOLID-LIQUID equilibria in the M<sup>I</sup>PO<sub>3</sub>-Cu(PO<sub>3</sub>)<sub>2</sub> systems.
- Authors
Marhag, C.; Hassen-Chehimi, Dalila B.; Said, H.
- Abstract
Thermodynamic exploration of solid-liquid equilibria of the MIPO3-Cu(PO3)2 (with MI=Li, Na, K, Rb, Cs, Ag, TI) systems is carried out with a semi-empirical equation of the liquidus curves. The enthalpies of fusion of pure polyphosphates and some intermediate compounds were determined from DTA curves. The temperature, enthalpy and entropy of fusion are calculated for each solid phase with the exception of silver polyphosphate and the intermediate compound Cs4Cu(PO3)6 which have very limited crystallization fields. The calculated values of the melting enthalpies are approximately equal to the measured ones. The melting enthalpy of Cu(PO3)2 calculated from different binary systems shows a wide variation in the obtained values, 35-54 kJ mol-1. The experimental value is 33.65 kJ mol-1. The calculated temperatures and compositions in most binary systems are in good agreement with experimental determinations.
- Subjects
SOLID-liquid equilibrium; PHASE equilibrium; THERMODYNAMICS; PHASE diagrams; THERMAL analysis; CALORIMETRY
- Publication
Journal of Thermal Analysis & Calorimetry, 2004, Vol 76, Issue 2, p417
- ISSN
1388-6150
- Publication type
Article