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- Title
The Synthesis and Structure of Hexakis(dimethylphenylphosphonite)ruthenium(II) bis[tetraphenylborate(-1)].
- Authors
Owalude, Samson O.; Odebunmi, Ezekiel O.; Eke, Uche B.; Tella, Adedibu C.; Rheingold, Arnold L.; Suib, Steven L.
- Abstract
Abstract. Treatment of the hydrazine salt [Ru(COD)(H2NNH2)4][BPh4]2 with excess of P(OMe)2Ph in acetone gave a homoleptic complex trans-[Ru{P(OMe)2Ph}6][BPh4]2, which was characterized by IR, 31P{1H}, 13C{1H}, and 1H NMR spectroscopy, elemental analysis, and X-ray crystallography. The ruthenium in the complex has distorted octahedral coordination arrangement and bonded to all the six P(OMe)2Ph molecules through the phosphorus atoms.
- Subjects
CHEMICAL synthesis; RUTHENIUM; TETRAPHENYLBORATES; NUCLEAR magnetic resonance; X-ray crystallography; PHOSPHORUS
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2014, Vol 640, Issue 2, p275
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201300422