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- Title
The Reducing Ability of Cycloheptatrienyl-Cyclopentadienyl Zirconium Sandwich Complexes towards Silver(I).
- Authors
Tagne Kuate, Alain C.; Pinkert, Lukas; Freytag, Matthias; Jones, Peter G.; Tamm, Matthias
- Abstract
The redox reaction between the cycloheptatrienyl-cyclopentadienyl zirconium sandwich complexes [(η7-C7H7)Zr(η5-C5 R5)] [ R = H ( 2a), R = Me ( 2b)] and three equivalents of silver(I) acetate, Ag(OAc), afforded [(η5-C5 R5)Zr(OAc)3] [ R = H ( 6a), R = Me ( 6b)] together with elemental silver and 7,7′-bi-1,3,5-cycloheptatriene ( 5). The molecular structures of 6a and 6b were established by X-ray diffraction analyses, revealing the presence of monomeric half-sandwich complexes with three acetato-κ2 O, O′ ligands.
- Subjects
ZIRCONIUM compounds synthesis; SILVER analysis; X-ray diffraction; LIGAND crystallography; MOLECULAR structure
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2013, Vol 639, Issue 14, p2386
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201300441