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- Title
Electrical ac and dc behavior of epoxy nanocomposites containing graphene oxide.
- Authors
Mancinelli, Paolo; Fabiani, Davide; Saccani, Andrea; Toselli, Maurizio; Fréchette, Michel F.
- Abstract
ABSTRACT This article deals with the investigation of electrical properties of epoxy-based nanocomposites containing graphene oxide nanofillers dispersed in the polymer matrix through two-phase extraction. Broadband dielectric spectroscopy and dc electrical conductivity as a function of electric field have been evaluated in specimens containing up to 0.5 wt % of nanofiller. Nanocomposites containing pristine graphene oxide do not show significant changes of electrical properties. On the contrary, the same materials after a proper thermal treatment at 135°C, able to provoke the in situ reduction of graphene oxide, exhibit higher permittivity and electrical conductivity, without showing large decrease of breakdown voltage. Moreover, a nonlinear behavior of the electrical conductivity is observed in the range of electric fields investigated, i.e. 2-30 kV mm−1. A new relaxation phenomenon with a very low temperature dependence is also evidenced at high frequency in reduced graphene oxide composites, likely associated to induced polarization of electrically conductive nanoparticles. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41923.
- Subjects
ALTERNATING currents; DIRECT currents; EPOXY compounds; NANOCOMPOSITE materials; GRAPHENE oxide
- Publication
Journal of Applied Polymer Science, 2015, Vol 132, Issue 18, pn/a
- ISSN
0021-8995
- Publication type
Article
- DOI
10.1002/app.41923