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- Title
[2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment.
- Authors
Kahl, Paul; Wagner, J. Philipp; Balestrieri, Ciro; Becker, Jonathan; Hausmann, Heike; Bodwell, Graham J.; Schreiner, Peter R.
- Abstract
The fusion of the sp3-hybridized parent diamondoid adamantane with the sp2-hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.
- Subjects
HYDROCARBON synthesis; HYDROCARBON analysis; FUSION (Phase transformation); ADAMANTANE; DIAMONDOIDS; FUNCTIONAL groups
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 32, p9277
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201602201