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- Title
A Self-Assembled [Fe<sup>II</sup><sub>12</sub>L<sub>12</sub>] Capsule with an Icosahedral Framework.
- Authors
Bilbeisi, Rana A.; Ronson, Tanya K.; Nitschke, Jonathan R.
- Abstract
How about a different geometry? Depending on the reaction conditions, a threefold‐symmetric triamine is observed to assemble into either the novel icosahedral [FeII12L12] capsule 1, or tetrahedral [FeII4L4] capsule 2. The two capsules have radically different cavity volumes and shapes, and are able to encapsulate guests of different size, shape, and charge.
- Subjects
MOLECULAR self-assembly; BACTERIAL capsules; NANOFABRICATION; HYDROGEN bonding; HIGH resolution spectroscopy; NUCLEAR magnetic resonance spectroscopy
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 34, p9027
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201302976