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- Title
Straightforward and Controlled Synthesis of Porphyrin–Phthalocyanine–Porphyrin Heteroleptic Triple‐Decker Assemblies.
- Authors
González‐Lucas, Daniel; Soobrattee, Shazia C.; Hughes, David L.; Tizzard, Graham J.; Coles, Simon J.; Cammidge, Andrew N.
- Abstract
A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide‐bridged heteroleptic porphyrin–phthalocyanine triple‐decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple‐decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.
- Subjects
ION traps; PORPHYRINS; DIPYRROMETHANES; METALLOPORPHYRINS; PHTHALOCYANINES; RARE earth metals
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 47, p10724
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202002500