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- Title
Macromolecular Isomerism in Giant Molecules.
- Authors
Shao, Yu; Yang, Shuguang; Zhang, Wen‐Bin
- Abstract
Macromolecular isomerism has been an important yet largely understudied subject. Giant molecules based on molecular nanoparticles exhibit properties highly dependent on the primary structures, providing a platform for such studies. Various isomers have been designed, synthesized and characterized, including sequence‐, regio‐, and topo‐isomers. The self‐assembly of these isomers is influenced by the distinct symmetry and collective interaction of each building block in a subtle and delicate way. The results suggest that isomerism may be exploited as a new way for fine‐tuning the structures and properties of macromolecules, which should be of great interest in both fundamental research and technical innovation.
- Subjects
ISOMERISM; MOLECULES; TECHNOLOGICAL innovations; MACROMOLECULES
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 14, p2985
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201904419