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- Title
Synthesis of benzyl chlorides and cycloveratrylene macrocycles using benzylic alcohols under homogeneous catalysis by HCl/dioxane.
- Authors
Vargas-Rodríguez, Yolanda Marina; Vargas, Melchor; Miranda, René; Francisco, Bernardo; Noguez, Olivia; Morales-Serna, José Antonio; Salmón, Manuel
- Abstract
The synthesis of benzyl chlorides, cyclic derivatives cyclotriveratrylene and cyclotripiperotrylene were carried out in using the HCl/dioxane system as a catalyst. The reaction proceeded with high selectivity and is sensitive to the number of alkyl and methoxy substituent on the aromatic ring.
- Subjects
BENZYL chloride; CHEMICAL synthesis; MACROCYCLIC compounds; HOMOGENEOUS catalysis; HYDROCHLORIC acid; DIOXANE; CHEMICAL reactions
- Publication
Organic Communications, 2012, Vol 5, Issue 2, p58
- ISSN
1307-6175
- Publication type
Article