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- Title
Electronic Structures of the Electron Transfer Series [M(bpy)<sub>3</sub>] <sup>n</sup>, [M(tpy)<sub>2</sub>] <sup>n</sup>, and [Fe(<sup>t</sup>bpy)<sub>3</sub>] <sup>n</sup> (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1-): A Mössbauer Spectroscopic and DFT Study
- Authors
England, Jason; Scarborough, Christopher C.; Weyhermüller, Thomas; Sproules, Stephen; Wieghardt, Karl
- Abstract
The five-membered electron-transfer series [M(bpy)3] n and [M(tpy)2] n (M = Fe, Ru; bpy = 2,2′-bipyridine, tpy = 2,2′:6′,2″-terpyridine) and [Fe(tbpy)3] n (tbpy = 4,4′-di- tert-butyl-2,2′-bipyridine; n = 3+, 2+, 1+, 0, 1-) have been investigated and the electronic structure of the so called 'low-valent' complexes ( n = 1+, 0, 1-) have been established by a combination of electro- and magnetochemistry, electron paramagnetic resonance (EPR) and Mössbauer spectroscopy, X-ray crystallography, and DFT calculations. These complexes are accessed by reduction of the d6 S = 0 dicationic starting materials [M(bpy)3]2+ and [M(tpy)2]2+ (M = Fe, Ru) and [Fe(tbpy)3]2+. The monocations [M(bpy ·)(bpy0)2]1+ ( S = 1/2) and [M(tpy ·)(tpy0)]1+ ( S = 1/2) (M = FeII, RuII) also contain a low-spin (t2g)6 divalent metal center, plus a single radical monoanion (bpy ·)1- or (tpy ·)1-, and two or one neutral (bpy0) or (tpy0) ligands, respectively. The unpaired electron resides in a ligand π* orbital. The neutral complexes [FeII(bpy ·)2(bpy0)]0 and [RuII(tpy ·)2]0 were found, by DFT calculations, to possess an S = 1 ground state that is attained by weak intramolecular ferromagnetic coupling between two ligand radical anions and a singlet excited state ( S = 0). In contrast, the neutral species [RuII(bpy ·)2(bpy0)]0 possesses an S = 0 ground state. The metal centers of these neutral complexes retain a low-spin (t2g)6 configuration. Remarkably, the corresponding neutral complex [FeII(tpy ·)2]0 contains high-spin FeII ( SFe = 2). Strong intramolecular antiferromagnetic metal-radical coupling yields an experimentally observed S = 1 ground state. The monoanions [MII(bpy ·)3]1- (M = Fe, Ru) are composed of a low-spin metal ion [Fe, Ru; (t2g)6; SM = 0] and three (bpy ·)1- radical anions.
- Subjects
CHARGE exchange; ELECTRONIC structure; COMPLEX compounds; ELECTROCHEMICAL research; MAGNETOCHEMISTRY; ELECTRON paramagnetic resonance; CHEMICAL reduction; DENSITY functional theory
- Publication
European Journal of Inorganic Chemistry, 2012, Vol 2012, Issue 29, p4605
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201200232