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- Title
Synthesis and Characterization of Bimetallic Single-Source Precursors (Ph<sub>3</sub>P)<sub>2</sub>M(µ-SEt)<sub>2</sub>E(SEt)<sub>2</sub> for MES<sub>2</sub> Chalcopyrite Materials (M = Cu, Ag and E = In, Ga, Al).
- Authors
Margulieux, Kelsey R.; Sun, Chivin; Kihara, Matthew T.; Colson, Adam C.; Zakharov, Lev N.; Whitmire, Kenton H.; Holland, Andrew W.; Pak, Joshua J.
- Abstract
We report the synthesis and characterization of I-III bimetallic complexes (Ph3P)2M(µ-SEt)2E(SEt)2 (M = Cu, Ag and E = In, Ga, Al), as well as (Ph3P)2M(µ-Cl)2ECl2 complexes isolated during their syntheses. The thiolate complexes can be used as single-source precursors (SSPs) to prepare various I-III chalcogenide semiconductor materials. The preparation of some SSPs of the series required minor variation in the reaction conditions. The organometallic complexes were structurally characterized by X-ray diffraction. The SSPs are compared in terms of their solid-state structures, basic reactivity, and potential suitability as precursors for chalcopyrite materials.
- Subjects
COMPLEX compounds synthesis; METAL complexes; BIMETALLIC catalysts; CHALCOPYRITE; THIOLATES; CHALCOGENIDES
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 13, p2068
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201700115