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- Title
Conversion of Cyclohexanones to Alkyl Aryl Ethers by Using a Pd/C-Ethylene System.
- Authors
El‐Deeb, Ibrahim Yussif; Tian, Miaomiao; Funakoshi, Tatsuya; Matsubara, Ryosuke; Hayashi, Masahiko
- Abstract
The conversion of cyclohexanone and substituted cyclohexanones into alkyl aryl ethers by using a Pd/C–ethylene system is discussed, with ethylene functioning as a hydrogen acceptor. The ether products are easily transformed into the corresponding phenols by treatment with BBr3. The direct conversion of cyclohexenone into phenol in the presence of a catalytic amount of Pd/C under an ethylene atmosphere is also described. The conversion of cyclohexanone and substituted cyclohexanones into alkyl aryl ethers by using a Pd/C–ethylene system is disclosed. The ether products are easily transformed into the corresponding phenols by treatment with BBr3. The direct conversion of cyclohexenone into phenol is also described.
- Subjects
CYCLOHEXANONES; ETHANOL; ETHYLENE receptors; PHENOL; DEHYDROGENATION
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 2, p409
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201601362