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- Title
Direct Metal-Catalyzed Regioselective Functionalization of Enamides.
- Authors
Gigant, Nicolas; Chausset‐Boissarie, Laëtitia; Gillaizeau, Isabelle
- Abstract
Enamides are stable enamine surrogates and provide key intermediates for the synthesis of small but complex nitrogen-containing compounds. Metal-catalyzed regioselective functionalization of enamides provides a rapid method to synthesize useful nitrogen containing heterocycles. This review discloses the recent progress made in the development of the CH functionalization of enamides involving efficient and atom-economical routes. Syntheses of different heterocycles are classified based on the site reactivity of enamides and key mechanistic insights are given for each transformation.
- Subjects
METAL catalysts; REGIOSELECTIVITY (Chemistry); ENAMINES; NITROGEN compound synthesis; HETEROCYCLIC compounds
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 25, p7548
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201402070