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- Title
SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2- (HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES.
- Authors
SAYIN, Elvan; KÜRKÇÜOĞLU, Güneş Süheyla
- Abstract
In this investigation, we present synthesis and characterized of three new heteropolynuclear cyanide complexes with 2- (Hydroxymethyl)pyridine (hmpH) of [M(H2O)(hmpH)Ni(CN)4]2·nH2O, (M(II) = Fe, Co and Ni); n = 12 for Fe, 2 for Co and Ni). The obtained complexes have been studied by elemental, thermal analysis, FT-IR, and Raman spectroscopic measurement techniques. Considering the alterations in characteristic peaks of cyanide, aqua, and hmpH ligands, general knowledge about the structural features of the complexes was detected from the vibrational spectra. The Ni(II) ion is coordinated by four cyanidecarbon atoms forming a square planar geometry. In addition, thermal analyses and electrical features of the complexes were investigated.
- Subjects
CYANIDES synthesis; PYRIDINE synthesis; HYDROXYMETHYL compounds; VIBRATIONAL spectra; THERMAL analysis; ELECTRIC properties
- Publication
Eskişehir Technical University Journal of Science & Technology A - Applied Sciences & Engineering, 2023, Vol 24, Issue 4, p216
- ISSN
2667-4211
- Publication type
Article
- DOI
10.18038/estubtda.1229463