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- Title
Investigation of the crystal structure of a dimeric rhodium(III) complex [(NH)Rh(μ-CO)(μ-OH)](NO)·HO.
- Authors
Vorob'eva, S.; Baidina, I.; Korol'kov, I.
- Abstract
A complex compound [(NH)Rh(μ-CO)(μ-OH)](NO)·HO has been obtained and structurally characterized. Crystal data: a = 7.9103(16) Å, b = 9.606(2) Å, c = 11.283(2) Å, α = 103.206(4)°, β = = 110.045(4)°, γ = 93.890(5)°, space group P-1, Z = 2, d = 2.335 g/cm. The crystal structure is a packing of dimeric complex rhodium cations [Rh(μ-OH)(μ-CO)(NH)], nitrate anions, and crystallization water molecules joined by a system of hydrogen bonds. The compound has been investigated with IR spectroscopy and powder X-ray diffraction. The isolated crystalline phase is poorly soluble in water.
- Subjects
METAL complexes; CRYSTAL structure; RHODIUM compounds; CRYSTALLIZATION; HYDROGEN bonding
- Publication
Journal of Structural Chemistry, 2016, Vol 57, Issue 8, p1588
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S002247661608014X