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- Title
Crystal structure refinement of fac-Co(NH<sub>2</sub>C<sub>2</sub>H<sub>4</sub>O)<sub>3</sub>·3H<sub>2</sub>O: Octahedron or trigonal prism?
- Authors
Virovets, A. V.; Mikhailenko, Yu. A.; Peresypkina, E. V.; Tkachev, S. V.; Cherkasova, T. G.
- Abstract
The compound fac-[Co(NH2CH2CH2O)3]•3H2O ( I) was synthesized and its crystal structure determined. Crystal data for C6H24CoN3O6: a = 14.5236(3) Å, c = 4.9346(2) Å, V = 901.43(5) Å3, T=90K, space group R3, Z=3, ρcalc = 1.620 g/cm3. In the complex, the octahedral environment of the Co(III) atom is formed by three monoethanolamine ligands using N and O atoms. The structure is disordered in such a way that the two oppositely orientated CoN3O3 octahedra are superimposed on each other at an angle.
- Subjects
COBALT; ATOMS; CRYSTALLOGRAPHY; COORDINATION compounds; AMINES
- Publication
Journal of Structural Chemistry, 2010, Vol 51, Issue 1, p190
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-010-0029-8