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- Title
Spectroscopic features of oxymethyl substituents in β-D-glucopyranosides and their characteristicity.
- Authors
Korolevich, M. V.; Piottukh-Peletskii, V. N.; Zhbankova, M. R.
- Abstract
In this paper we studied whether the spectral features of the oxymethyl group in methyl-β-D-glucopyranoside with an additional oxymethyl substituent are characteristic. We also investigated the possibilities of using these features in spectral analysis. This study was based on our complete calculations of the frequencies and forms of the normal vibrations and the absolute intensities of the IR absorption bands of the 4-O-methyl-β-methyl-D-glucopyranoside molecule and comparison of the results and the theoretical absorption curve of this compound with the corresponding data for methyl-β-D-glucopyranoside, 2,3-, 2,6-, and 3,6-di-O-nitromethyl-β-D-glucopyranoside, and 4-O-methyl-2,3-di-O-nitromethyl-β-D-glucopyranoside.
- Subjects
ABSORPTION; CHEMICAL structure; INFRARED spectroscopy; VIBRATION (Mechanics); PHYSICAL &; theoretical chemistry
- Publication
Journal of Structural Chemistry, 2008, Vol 49, Issue 1, p31
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-008-0005-8