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- Title
SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)<sub>2</sub>RuCl<sub>2</sub>].
- Authors
KILIÇARSLAN, Fatma Aytan; ERDOĞMUŞ, Ali; MANAV YALÇIN, Sabiha; GÜL, Ahmet
- Abstract
In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess (bpy)2RuII moieties directly attached to the β position in the (ethylsulfanyl) porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, ¹H-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of (bpy)2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.
- Subjects
PORPHYRAZINES; SULFIDES analysis; RUTHENIUM compounds; CHELATION; BIPYRIDINE; NUCLEAR magnetic resonance spectroscopy
- Publication
Sigma: Journal of Engineering & Natural Sciences / Mühendislik ve Fen Bilimleri Dergisi, 2018, Vol 36, Issue 2, p487
- ISSN
1304-7191
- Publication type
Article