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- Title
Reactivity of Octa(2,6-fluorophenyl)porphyrazine in Acid–Base Reactions with Nitrogenous Organic Bases.
- Authors
Petrov, O. A.; Gamov, G. A.; Chizhova, N. V.; Mamardashvili, N. Zh.
- Abstract
Reactions between octa(2,6-fluorophenyl)porphyrazine and pyridine, 2-methylpyridine, morpholine, piperidine, butylamine, tert-butylamine, diethylamine, and triethylamine in a benzene medium have been studied. The acid–base reactions between the macroheterocycle and piperidine or butylamine are slow processes leading to the formation of kinetically stable proton-transfer complexes. The structures of these complexes have been optimized using CAM-B3LYP/cc-pVTZ. The changes in the reactivity of octa(2,6-fluorophenyl)porphyrazine are analyzed as a function of the steric structure and proton-acceptor power of the nitrogenous base.
- Subjects
BASE pairs; ORGANIC bases; DIETHYLAMINE; PIPERIDINE; MORPHOLINE
- Publication
Russian Journal of Organic Chemistry, 2024, Vol 60, Issue 5, p827
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428024050051