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- Title
A Rapid Route to Aminocyclopropanes via Carbamatoorganozinc Carbenoids.
- Authors
Ishikawa, Shingo; Sheppard, Tom D.; D'Oyley, Jarryl M.; Kamimura, Akio; Motherwell, William B.
- Abstract
The article presents a study which aims to develop a simple method for carbamate-protected aminocyclopropanes through hitherto unknown carbamatoorganozinc carbenoids. It states that the mild reaction was undertaken at room temperature and with a preference for the formation of cis or endo isomer. It adds that deprotection was achieved using iodotrimethylsilane.
- Subjects
CARBAMATES; AMINOCYCLOPROPANECARBOXYLATE synthase; ORGANOZINC compounds; ISOMERS; METHYLSILANE
- Publication
Angewandte Chemie, 2013, Vol 125, Issue 38, p10244
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201304720