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- Title
Synthesis of meta-Carboranyl-(S)-homocysteine Sulfoxide.
- Authors
Gruzdev, D. A.; Ustinova, V. O.; Levit, G. L.; Ol'shevskaya, V. A.; Krasnov, V. P.
- Abstract
New (S)-homocysteine derivatives containing a meta-carborane fragment were synthesized. m-Carboranyl-(S)-homocysteine sulfoxide was obtained as a mixture of diastereoisomers. The reduction of the side-chain carboxy group of N-tert-butoxycarbonyl-(S)-aspartic acid α-tert-butyl ester with sodium tetrahydridoborate was not accompanied by racemization.
- Subjects
SULFOXIDES synthesis; HOMOCYSTEINE; RACEMIZATION; SULFOXIDE derivatives; DIASTEREOISOMERS; CHEMICAL reduction
- Publication
Russian Journal of Organic Chemistry, 2018, Vol 54, Issue 10, p1579
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428018100251