We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Optimization of Electrochemically Deposited Highly Doped ZnO Bilayers on Ga-Rich Chalcopyrite Selenide for Cost-Effective Photovoltaic Device Technology.
- Authors
Papadimitriou, Dimitra N.; Roupakas, Georgios; Roumeliotis, Georgios G.; Vogt, Patrick; Köhler, Tristan
- Abstract
High quality polycrystalline bilayers of aluminium doped ZnO (Al:ZnO) were successively electrodeposited in the form of columnar structures preferentially oriented along the (1011) crystallographic direction from aqueous solution of zinc nitrate (Zn(NO3)2) at negative electrochemical potential of EC = (-0.8)-(-1.2) V and moderate temperature of 80 °C on gallium rich (30% Ga) chalcopyrite selenide Cu(In,Ga)Se2 (CIGS) with chemically deposited ZnSe buffer (ZnSe/Cu(In,Ga)Se2/Mo/glass). The aluminium doped ZnO layer properties have initially been probed by deposition of Al:ZnO/i-ZnO bilayers directly on Mo/glass substrates. The band-gap energy of the Al:ZnO/i-ZnO reference layers was found to vary from 3.2 to 3.7 eV by varying the AlCl3 solute dopant concentration from 1 to 20 mM. The electrical resistivity of indium-pellet contacted highly doped Al:ZnO sheet of In/Al:ZnO/i-ZnO/Mo/glass reference samples was of the order ρ ~10-5 Ω·cm; the respective carrier concentration of the order 1022 cm-3 is commensurate with that of sputtered Al:ZnO layers. For crystal quality optimization of the bilayers by maintenance of the volatile selenium content of the chalcopyrite, they were subjected to 2-step annealing under successive temperature raise and N2 flux regulation. The hydrostatic compressive strain due to Al3+ incorporation in the ZnO lattice of bilayers processed successively with 5 and 12 mM AlCl3 dopant was "h = -0.046 and the respective stress εh = -20 GPa. The surface reflectivity of maximum 5% over the scanned region of 180-900 nm and the (optical) band gap of Eg = 3.67 eV were indicative of the high optical quality of the electrochemically deposited (ECD) Al:ZnO bilayers.
- Subjects
CHALCOPYRITE; POLYCRYSTALS; CRYSTALLOGRAPHY; INDIUM; GALLIUM
- Publication
Energies (19961073), 2016, Vol 9, Issue 11, p951
- ISSN
1996-1073
- Publication type
Article
- DOI
10.3390/en9110951