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- Title
A Molecular "A‐Type" Tangled Metallocube.
- Authors
Ma, Li‐Li; Li, Yang; Li, Xin; Zhang, Le; Sun, Li‐Ying; Han, Ying‐Feng
- Abstract
Tangled cubes feature the topology of typical Platonic cubes, with their "faces" traversed by edges in different ways. This study generates an "A‐type" tangled metallocube from the reaction of binuclear gold‐NHC complex and H2S. The tangled cube topology was validated by multinuclear nuclear magnetic resonance (NMR) spectroscopy, high‐resolution electrospray‐ionization (HR‐ESI) mass spectrometry, and single‐crystal X‐ray diffraction analysis. This study offers a simple and effective approach to designing and fabricating new, topologically unique molecular structures.
- Subjects
NUCLEAR magnetic resonance; MASS spectrometry; MOLECULAR structure; X-ray diffraction; CUBES
- Publication
Angewandte Chemie, 2022, Vol 134, Issue 35, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202208376