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- Title
Recent Advances in the Nickel-Catalyzed Alkylation of C-H Bonds.
- Authors
Požgan, Franc; Grošelj, Uroš; Svete, Jurij; Štefane, Bogdan; Al Mamari, Hamad H.
- Abstract
Functionalization of C-H bonds has emerged as a powerful strategy for converting inert, nonfunctional C-H bonds into their reactive counterparts. A wide range of C-H bond functionalization reactions has become possible by the catalysis of metals, typically from the second row of transition metals. First-row transition metals can also catalyze C-H functionalization, and they have the merits of greater earth-abundance, lower cost and better environmental friendliness in comparison to their second-row counterparts. C-H bond alkylation is a particularly important C-H functionalization reaction due to its chemical significance and its applications in natural product synthesis. This review covers Ni-catalyzed C-H bond alkylation reactions using alkyl halides and olefins as alkyl sources.
- Subjects
ALKYLATION; HALOALKANES; NATURAL products; ENVIRONMENTAL economics
- Publication
Molecules, 2024, Vol 29, Issue 9, p1917
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules29091917