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- Title
Synthesis, crystal structure, and magnetic properties of an azido-bridged Mn(II) complex [C<sub>3</sub>H<sub>5</sub>NH<sub>3</sub>][Mn(N<sub>3</sub>)<sub>3</sub>].
- Authors
Kun Qian; Yiyong Xu; Zengtao Wang; Jie Yang
- Abstract
A new compound [C3H5NH3][Mn(N3)3] has been synthesized, in which the Mn2+ ions are connected by the end-to-end azide anions to form the 3D architecture, while the C3H5NH3+ cations reside in the cavities of the Mn2+-N3- network, forming rich N-H···N hydrogen bonds with the terminal N atoms of the azide anions. The complex has been characterized by IR spectroscopy, elemental analyses, and magnetic measurements. Magnetic susceptibility data indicate antiferromagnetic interaction among the MnII ions.
- Subjects
CHEMICAL synthesis; MANGANESE compounds; MAGNETIC properties of manganese compounds; CRYSTAL structure; METAL ions; HYDROGEN bonding
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2017, Vol 72, Issue 6, p409
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2016-0267