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- Title
Reactivity of α-Amino Acids in the Reaction with Esters in Aqueous-1,4-Dioxane Media.
- Authors
Kochetova, L. B.; Kustova, T. P.; Kuritsyn, L. V.
- Abstract
The kinetics of the reaction of a series of α-amino acids with 4-nitrophenyl acetate, 4-nitrophenyl benzoate, and 2,4,6-trinitrophenyl benzoate in aqueous 1,4-dioxane medium has been studied. Kinetics of the reactions involving 4-nitrophenyl acetate and 2,4,6-trinitrophenyl benzoate has complied with the Brønsted dependence and revealed linear correlation between rate constant logarithm and the energy difference of the frontier orbitals of α-amino acids anions.
- Subjects
AMINO acids; ESTERS; NITROPHENYL compounds; BRONSTED acids; REACTIVITY (Chemistry)
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 1, p80
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218010127