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- Title
Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones into 3,4-dimethylphenol.
- Authors
Gavrilova, G. V.; Moiseeva, A. A.; Beloglazkina, E. K.; Gavrilov, A. A.; Zyk, N. V.
- Abstract
Electrochemical behavior of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones and 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-one was studied. Reductive dehalogenation of cyclohexa-2,5-dien-1-ones having a halogen atom at the neopentyl-like carbon atom gives the corresponding carbanion which undergoes anionic cyclopropyl-allyl rearrangement with subsequent addition of proton to form 3,4-dimethylphenol.
- Subjects
ELECTROCHEMICAL analysis; QUANTITATIVE chemical analysis; ALICYCLIC compounds; CYCLOHEXANE; ETHYLENE dibromide
- Publication
Russian Journal of General Chemistry, 2009, Vol 79, Issue 2, p264
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363209020169