Poly(dibenzosilole)s are an emerging class of polymers with similar optoelectronic properties to polyfluorenes. With increased stability towards oxidation, several poly(dibenzosilole)-based devices, such as light emitting diodes, have shown improved performance over their polyfluorene counterparts. As a consequence of reduced conjugation in the polymer chain, some poly(dibenzosilole)s have high triplet excited state energies, which make them suitable hosts for blue triplet emitters in electrophosphorescent devices.