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- Title
Hard‐Sphere Random Close‐Packed Au<sub>47</sub>Cd<sub>2</sub>(TBBT)<sub>31</sub> Nanoclusters with a Faradaic Efficiency of Up to 96 % for Electrocatalytic CO<sub>2</sub> Reduction to CO.
- Authors
Zhuang, Shengli; Chen, Dong; Liao, Lingwen; Zhao, Yan; Xia, Nan; Zhang, Wenhao; Wang, Chengming; Yang, Jun; Wu, Zhikun
- Abstract
Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well‐defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two‐phase anti‐galvanic reduction (AGR) method is presented for precisely tailoring Au44(TBBT)28 to produce Au47Cd2(TBBT)31 nanoclusters with a hard‐sphere random close‐packed structure, exhibiting Faradaic efficiencies of up to 96 % at −0.57 V for the electrocatalytic reduction of CO2 to CO.
- Subjects
METALS; CADMIUM
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 8, p3097
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201912845