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- Title
Gold(I)‐Catalyzed Tandem Cycloisomerization of 1,5‐Enyne Ethers by Hydride Transfer.
- Authors
Lu, Xiao‐Lin; Lyu, Mao‐Yun; Peng, Xiao‐Shui; Wong, Henry N. C.
- Abstract
Abstract: A novel gold‐catalyzed tandem protocol, initiated by hydride transfer in the presence of catalytic (C6F5)3PAuCl/AgSbF6, for the formation of fused polycyclic ring systems has been achieved. This tandem reaction provides rapid access to various fused polycyclic species in a single chemical operation, leading to stereospecific formation of two carbon–carbon bonds and three rings.
- Subjects
GOLD catalysts; CYCLOISOMERIZATION; HYDRIDE transfer reactions; POLYCYCLIC compounds; CARBON-carbon bonds
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 35, p11535
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201806842