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- Title
Iron-Catalyzed Regioselective Transfer Hydrogenative Couplings of Unactivated Aldehydes with Simple Alkenes.
- Authors
Zheng, Yan ‐ Long; Liu, Yan ‐ Yao; Wu, Yi ‐ Mei; Wang, Yin ‐ Xia; Lin, Yu ‐ Tong; Ye, Mengchun
- Abstract
An FeBr3-catalyzed reductive coupling of various aldehydes with alkenes that proceeds through a direct hydride transfer pathway has been developed. With iPrOH as the hydrogen donor under mild conditions, previously challenging coupling reactions of unactivated alkyl and aryl aldehydes with simple alkenes, such as styrene derivatives and α-olefins, proceeded smoothly to furnish a diverse range of functionalized alcohols with complete linear regioselectivity.
- Subjects
REGIOSELECTIVITY (Chemistry); STEREOCHEMISTRY; ALDEHYDES; ALKENES; CHEMICAL structure
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 21, p6423
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201602130