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- Title
Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates.
- Authors
Chizhova, N. V.; Shinkarenko, A. V.; Mamardashvili, N. Zh.
- Abstract
Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy.
- Subjects
CHEMICAL reactions; TIN; CADMIUM compounds synthesis; EXCHANGE reactions; NUCLEAR magnetic resonance spectroscopy
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 12, p2559
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218120162