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- Title
Transition metal complexes with 2,6-Di-<i>tert</i>-butyl-<i>p</i>-quinone 1′-phthalazinylhydrazone.
- Authors
Levchenkov, S. I.; Shcherbakov, I. N.; Popov, L. D.; Lyubchenko, S. N.; Suponitskii, K. Yu.; Tsaturyan, A. A.; Beloborodov, S. S.; Kogan, V. A.
- Abstract
2,6-Di- tert-butyl- p-quinone 1′-phthalazinylhydrazone (HL) was synthesized. Quantum-chemical calculations of the energy of possible tautomeric forms of the hydrazone were performed. The complexes of Zn(II), Hg(II), Ni(II), and Cu(II) of ML 2 composition were obtained and studied. The structure of the NiL 2 complex was established by XRD. It was shown by DFT-D3 calculations that the cis-structure of the complex is stabilized due to the interligand dispersion interaction.
- Subjects
TRANSITION metals; HYDRAZONES; QUANTUM chemistry; CHEMICAL synthesis; AZO compounds
- Publication
Russian Journal of General Chemistry, 2013, Vol 83, Issue 10, p1928
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363213100216