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- Title
Design, Synthesis, and Biological Activity of Oxime Ether Strobilurin Derivatives Containing Indole Moiety as Novel Fungicide.
- Authors
Xie, Ya ‐ Qiang; Huang, Zi ‐ Long; Yan, Hui ‐ Dong; Li, Jun; Ye, Li ‐ Yi; Che, Li ‐ Ming; Tu, Song
- Abstract
Twenty-one novel oxime ether strobilurins containing indole moiety, which employed an indole group to stabilize the E-styryl group in Enoxastrobin, were designed and synthesized. The biological assay indicated that most compounds exhibited potent fungicidal activities. The structure-activity relationship study demonstrated that the synthesized methyl 3-methoxypropenoate oxime ethers 7b-e exhibited remarkably high activities among all the synthesized oxime ether compounds 7. Moreover, the fungicidal activities of methyl α-(methoxyimino)benzeneacetate oxime ethers compounds 7f-i and N-methoxy-carbamic acid methyl esters compounds 7j-m showed significant differences compared to the corresponding products of ammonolysis.
- Subjects
OXIMES; CHEMICAL synthesis; STROBILURINS; INDOLE compounds; FUNGICIDES
- Publication
Chemical Biology & Drug Design, 2015, Vol 85, Issue 6, p743
- ISSN
1747-0277
- Publication type
Article
- DOI
10.1111/cbdd.12460