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- Title
BN Heterosuperbenzenes: Synthesis and Properties.
- Authors
Wang, Xiao ‐ Ye; Wang, Jie ‐ Yu; Pei, Jian
- Abstract
Replacement of CC unit with its isoelectronic BN unit in aromatics provides a new class of molecules with appealing properties, which have attracted great attention recently. In this Concept, we focus on BN-substituted polycyclic aromatics with fused structures, and review their synthesis, photophysical, and redox properties, as well as their applications in organic electronics. We also present challenging synthetic targets, large BN- substituted polycyclic aromatics, such as regioregular BN heterosuperbenzenes, which can be viewed as BN-doped nanographenes. Finally, we propose an atomically precise bottom-up synthesis of structurally well-defined BN-doped graphenes.
- Subjects
CHEMICAL synthesis; ISOELECTRONIC sequences; AROMATIC compounds; ORGANIC electronics; POLYCYCLIC aromatic compounds; GRAPHENE
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 9, p3528
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201405627