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- Title
Drastic Enhancement of Catalytic Activity via Post-oxidation of a Porous Mn<sup>II</sup> Triazolate Framework.
- Authors
Liao, Pei‐Qin; Li, Xu‐Yu; Bai, Jie; He, Chun‐Ting; Zhou, Dong‐Dong; Zhang, Wei‐Xiong; Zhang, Jie‐Peng; Chen, Xiao‐Ming
- Abstract
MnIII is a powerful active site for catalytic oxidation of alkyl aromatics, but it can be only stabilized by macrocyclic chelating ligands such porphyrinates. Herein, by using benzobistriazolate as a rigid bridging ligand, a porous MnII azolate framework with a nitrogen-rich coordinated environment similar to that of metalloporphyrins was synthesized, in which the MnII ions can be post-oxidized to MnIII to achieve drastic increase of catalytic (aerobic) oxidation performance.
- Subjects
CATALYTIC activity; POROUS materials; MAGNESIUM; CHELATING agents; METALLOPORPHYRINS; OXIDATION
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 36, p11303
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201403123