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- Title
Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition.
- Authors
Magrez‐Chiquet, Magaly; Morin, Marie S. T.; Wencel‐Delord, Joanna; Drissi Amraoui, Sammy; Baslé, Olivier; Alexakis, Alexandre; Crévisy, Christophe; Mauduit, Marc
- Abstract
CC coupling: DiPPAM 1 and BINAP 2 ligands led to divergent behaviors in the asymmetric conjugate addition (ACA) of dialkylzinc reagents to linear aryldienones, which were applied to the development of a highly selective sequential asymmetric 1,6/1,4‐ACA process (see scheme; Tf = triflate, DBU = 1,8‐diazabicyclo[5.4.0]undec‐7‐ene).
- Subjects
CHEMICAL research; ENANTIOSELECTIVE catalysis; DIALKYLZINC; CONJUGATE addition reactions; CHEMICAL bonds; LIGANDS (Chemistry)
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 41, p13663
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302649