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- Title
Desulfinative palladium‐catalyzed cross‐coupling of arylsulfonyl hydrazides with aryl bromides under air.
- Authors
Liu, Qingling; Yang, Bo
- Abstract
A highly efficient and mild palladium‐catalyzed cross‐coupling of arylsulfonyl hydrazides and aryl bromides for the selective synthesis of unsymmetrical biaryls has been developed. This methodology has the advantages of easily accessible starting materials, functional group tolerance and a wide range of substrates, which provide rapid access to biaryls derivatives. In this protocol, abundant and stable aryl bromides serve as the aryl sources by coupling reaction of the aryl group generated from arylsulfonyl hydrazides via in situ release of nitrogen and sulfur dioxide. No external oxidants or acids are needed for this kind of transformation.
- Subjects
ARYL bromides; HYDRAZIDES; COUPLING reactions (Chemistry); ARYL group; NITROGEN dioxide; SULFUR dioxide; FUNCTIONAL groups
- Publication
Applied Organometallic Chemistry, 2019, Vol 33, Issue 10, pN.PAG
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.5140