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- Title
Novel synthesis of highly functionalized cyclopentane derivatives via [3 + 2] cycloaddition reactions of donor–acceptor cyclopropanes and (E)-3-aryl-2-cyanoacrylates.
- Authors
Chenlu Dai; Mingshuang Li; Mengjun Chen; Naili Luo; Cunde Wang
- Abstract
An efficient [3 + 2] cycloaddition reaction of cyanocyclopropanecarbonates and (E)-3-aryl-2-cyanoacrylates mediated by 1,8-diazabicyclo[5.4.0]undec-7-ene for the synthesis of highly functionalized cyclopentane derivatives in moderate to good yields (79%−87%) was developed. The structures of two typical products were confirmed by X-ray crystallography.
- Subjects
RING formation (Chemistry); CYCLOPENTANE derivatives; CYCLOPROPANE derivatives; X-ray crystallography
- Publication
Journal of Chemical Research, 2019, Vol 43, Issue 1/2, p43
- ISSN
1747-5198
- Publication type
Article
- DOI
10.1177/1747519819831883