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- Title
Pd/Zn(OTf)<sub>2</sub> Co‐Catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen.
- Authors
Gao, Yang; Yang, Fan; Pu, Dongdong; Laishram, Ronibala Devi; Fan, Ruifeng; Shen, Guoli; Zhang, Xuexin; Chen, Jingchao; Fan, Baomin
- Abstract
An efficient method for the asymmetric hydrogenation of cyclic and acyclic N‐sulfonylimines co‐catalyzed by Pd/Zn(OTf)2 using hydrogen gas under ambient pressure was developed. The methodology offers an easy access to generate chiral sulfonylamines in good yields and excellent enantioselectivities. Chiral sulfonylamines can be efficiently synthesized in good yields by asymmetric hydrogenation of cyclic and acyclic N‐sulfonylimines co‐catalyzed by Pd/Zn(OTf)2 using hydrogen gas under ambient pressure.
- Subjects
HYDROGENATION; IMINES; HYDROGEN; SULFONYL compounds; CHIRALITY
- Publication
European Journal of Organic Chemistry, 2018, Vol 2018, Issue 45, p6274
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201801123