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- Title
Photocatalytic Reduction of CO<sub>2</sub> by TiO<sub>2</sub> Nanotubes.
- Authors
Chang, H.-H.; Wei, L.-W.; Huang, H.-L.; Chang, H.-Y.; Wang, H. Paul
- Abstract
Continuously increasing atmospheric concentrations of CO2 have given rise to great concerns about climate change. Photocatalytic reduction of CO2 to chemicals by solar energy is considered a green and sustainable process. Interactions between CO2 molecules and photocatalysts surfaces are the key factors that affect photocatalytic reduction efficiency. Thus, a better understanding of their reactive species on the TiO2 nanotube (TNT) surfaces by in situ FTIR spectroscopy was studied in the present work. The FTIR absorbance features at 1303 cm − 1 and 1393 cm − 1 were associated with carbonate species, e.g., bidentate carbonate on the TNT. Complete desorption of CO2 from the TNT occurred at T > 4 1 8 K. The carboxylate species that were adsorbed on the TNT may conduct the surface reactions enhanced by UV–Vis light to yield low carbon chemicals. A better understanding of reactive species on the TiO2 nanotube (TNT) surfaces by in situ FTIR spectroscopy was studied. The FTIR absorbance features at 1303 and 1393 cm–1 were associated with carbonate species, e.g., bidentate carbonate on the TNT. Complete desorption of CO2 from the TNT occurred at T > 418 K. The carboxylate species that were adsorbed on the TNT may conduct the surface reactions enhanced by UV–Vis light to yield low carbon chemicals.
- Subjects
NANOTUBES; FOURIER transform infrared spectroscopy; CHEMICAL reduction; SURFACE reactions; CHEMICAL energy; PHOTOREDUCTION
- Publication
NANO, 2022, Vol 17, Issue 4, p1
- ISSN
1793-2920
- Publication type
Article
- DOI
10.1142/S1793292022500321