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- Title
XRD and EXAFS study of nitrato ammine complexes of nitrosyl ruthenium.
- Authors
Kabin, E.; Emel'yanov, V.; Baidina, I.; Nedoseykina, T.; Vorob'yov, V.
- Abstract
The structure of trans-[RuNO(NH)(HO)](NO) ( I) and trans-[RuNO(NH)(NO)](NO) ( II) was determined by XRD. Crystallographic data are as follows: space group I4/ a; a = b = 18.280(1) Å, c = 15.129(1) Å, R = 0.0244 ( I), and space group Cm, a = 11.5620(3) Å, b = 7.9934(2) Å, c = 7.7864(2) Å, β = 127.124(1)°, R = 0.0139 ( II). Interatomic distances for complex particles of fac- and mer- [RuNO(NH)(NO)] ( III and IV, respectively) were determined by EXAFS.
- Subjects
X-ray diffraction; EXTENDED X-ray absorption fine structure; COMPLEX compounds; NITROSYL chloride; RUTHENIUM; CRYSTALLOGRAPHY; CHEMICAL structure
- Publication
Journal of Structural Chemistry, 2010, Vol 51, p73
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-010-0192-y