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- Title
Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines.
- Authors
Friedman, Adam A.; Panteleev, Jane; Tsoung, Jennifer; Huynh, Vaizanne; Lautens, Mark
- Abstract
The article discusses a study which examines the relevance of domino catalysis in chiral and achiral ligand synthesis. It says that domino catalysis is a fundamental strategy for synthesis of a heterocyclic scaffolds. It states that domino process is associated with the electronic properties of vinyl pyridine. It reveals that the said reaction leads to the development of an aza-dihydrodibenzoxepines through arylation and coupling reaction.
- Subjects
CATALYSIS research; DOMINO toppling; HETEROCYCLIC compounds synthesis; ENANTIOSELECTIVE catalysis; LIGAND biosynthesis; ARYLATION; COUPLING reactions (Chemistry)
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 37, p9755
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201303659