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- Title
Comparison of the Reactivity of Nonheme Iron(IV)-Oxo versus Iron(IV)-Imido Complexes: Which is the Better Oxidant?
- Authors
Vardhaman, Anil Kumar; Barman, Prasenjit; Kumar, Suresh; Sastri, Chivukula V.; Kumar, Devesh; de Visser, Sam P.
- Abstract
Which is better? The first detailed comparison of the reactivity of nonheme iron(IV)–imido versus nonheme iron(IV)‐oxo intermediates with substrates is presented. The iron(IV)–imido variant reacts with sulfides five times faster than iron(IV)–oxo, whereas the reverse trend is observed for hydrogen atom abstraction. These observed trends are analyzed and explained.
- Subjects
IRON imides; OXO compounds; BIOTRANSFORMATION (Metabolism); HORMONE synthesis; OXIDIZING agents; ELECTRON affinity
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 47, p12288
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201305370