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- Title
(Arene)ruthenium Complexes with Imidazolin-2-imine and Imidazolidin-2-imine Ligands.
- Authors
Tönnemann, Justus; Scopelliti, Rosario; Severin, Kay
- Abstract
Imidazolin-2-imine and imidazolidin-2-imine ligands are versatile N donors in transition metal chemistry. Here, we describe the synthesis and characterization of (arene)Ru complexes with these ligands. Simple adducts of the type [( p-cymene)Ru(L)Cl2] (L = 1,3-diarylimidazolin-2-imine or 1,3-dimesitylimidalzolidin-2-imine) can be converted into complexes in which the imines act as π ligands with tethered imine groups. Furthermore, the high basicity of the N donor group can promote self-activation of the (arene)Ru complexes.
- Subjects
RUTHENIUM compound synthesis; IMIDAZOLINES; LIGANDS (Chemistry); LIGAND exchange reactions; RUTHENIUM; TRANSITION metal complexes; TRANSITION metal compounds synthesis
- Publication
European Journal of Inorganic Chemistry, 2014, Vol 2014, Issue 26, p4287
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201402583