We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Crystal structure of tris(triphenylsiloxy)borane·triphenylsilanol (1:1) adduct.
- Authors
Beckett, Michael; Hibbs, David; Hursthouse, Michael; Malik, K.; Owen, Paul; Varma, K.
- Abstract
The title compound crystallizes in the triclinic space group $$P \bar 1$$ , with a = 14.458(6), b = 14.630(5), c = 14.721(8) Å, α = 79.75(2), β = 80.11(3), γ = 80.50(3)°, and Z = 2. The crystal structure consists of molecules of (Ph3SiO)3B and Ph3SiOH linked by an weak B···(silanol) acceptor-donor bond, additionally stabilized by OH(silanol)···O(siloxy) hydrogen bonds. The average B–O, Si–O distances and B–O–Si angle are 1.369, 1.649 Å and 137.2°, respectively.
- Publication
Journal of Chemical Crystallography, 1998, Vol 28, Issue 4, p277
- ISSN
1074-1542
- Publication type
Article
- DOI
10.1023/A:1021849219098