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- Title
A Simple Method for the Formation of α‐Thioalkyl Radicals and the Promotion of Carbon‐Carbon Bond Formation by Photoirradiation of Electron Donor‐Acceptor Complexes.
- Authors
Roy, Pijush Kanti; Hitomi, Yutaka
- Abstract
This study documents the formation of an electron donor‐acceptor complex between thioanisole and benzylidenemalononitrile. Upon irradiation, the electron donor‐acceptor complex generates α‐thioalkyl radicals, facilitating carbon‐carbon bond formation. Mechanistic investigations underscore the crucial roles of both one‐electron oxidation and deprotonation processes in achieving a reaction yield up to 43 %.
- Subjects
ELECTRON donor-acceptor complexes; CARBON-carbon bonds; RADICALS (Chemistry); CHEMICAL yield; PROTON transfer reactions
- Publication
Asian Journal of Organic Chemistry, 2023, Vol 12, Issue 10, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202300378